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8. ALIPHATIC HYDROCARBONS                                                 eLearn.Punjab

Q. 4. Write the structural formula for each of the following compounds

,

i) 2-Methylpropane.                             ii) Neopentane.

iii) 3-Ethylpentane.                        iv) 4-Ethyl-3,4-dimethylheptane.

v) 2,2,3,4-Tetramethylpentane                   vi) 4-iso-Propylheptane.

vii) 2,2-Dimethylbutane.                        viii) 2,2-Dimethylpropane.

Q. 5. Write down names of the following compounds according to
    IUPAC-system.

( ) ( ))i(
                                    )ii(           CH3     C      CH2     C CH3 3

                                                          3

)iii( )iv(                                         (CH3  )   CH      CH   CH  (CH3  )
                                                          2            |             2

                                                                  CH3

)v( CH3CH2C(CH3 )2CH(CH2CH3 )CH3 )vi(           (  CH3CH2    )   CH
                                                              3

( ))vii( CH3C(CH3 )2 CH2 2 CH3      )viii(         (C6H5  )   CH
                                                           3

Q. 6. What are the rules for naming alkanes? Explain with suitable examples.
Q. 7.(a) Write down the structural formulas for all the isomeric hexanes and name

      them according to IUPAC system

(b) The following names are incorrect. Give the correct IUPAC names,

   i) 4-Methylpentane                           ii) 3,5,5-Trimethylhexane
   iii) 2-Methyl-3-Ethylbutane

Q.8. (a) Explain why alkanes are less reactive than alkenes? What is the effect of

   branching on the melting point of alkanes ?

   (b) Three different alkanes yield 2-methylbutane when they are hydrogenated

   in the presence of a metal catalyst. Give their structures and write equations

   for the reactions involved.

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